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Alkylation of aromatics occurs when a mixture of aromatic and saturated hydrocarbons are treated at room temperature with a mixture of a Lewis acid (AlCI 3 , FeCI 3 , ZnCI 2 ) and a higher-valent metal halide as oxidant (CuCI 2 , FeCI3 ).189 The reaction of isopentane with benzene, for example, resulted in the formation of 40% of isomeric pentylbenzenes (neopentylbenzene, 2-methyl-2-phenylbutane, 2-methyl-3phenylbutane) together with smaller amounts of isopropylbenzene, ethylbenzene, and 1,1-diphenylethane. p-Polyphenyl was also detected (12%). Similar results were obtained in alkylation of benzene with ethylbenzene (40-45% yield of 1,1diphenylethane), whereas only a trace of cyclohexylbenzene was found in the reaction with cyclohexane. When, however, the latter reaction was carried out in the presence of isopentane, cyclohexylbenzene was isolated in 20% yield. Isopentane promoted alkylation of benzene with other saturated hydrocarbons as well. Increased yields were achieved when CuCl 2 was regenerated in situ by carrying out the alkylation reaction in the presence of oxygen (air).

The lateral magnification will be positive, and the image will be erect, except when an odd-m image is virtual. Two special cases (which can be combined) are of interest: 1) if the illumination is collimated, the image size will be independent of the reconstructing wavelength; 2) if the reference beam is also collimated, the magnification will be unity, regardless of object distance. Comparing the longitudinal and lateral magnifications, Eqs. (22) and (27), we find that

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According to the specification, if a user receives n consecutive frames with the BECN bit set to a 1 bit, the traffic should be reduced from the user by a step below the current sending or offered rate. The step count (S) is defined in the following order: 0.675 times throughput 0.5 times throughput 0.25 times throughput In the same fashion, traffic can be built up after receiving n/2 consecutive frames with the BECN bit set to a 0 bit. The rate is increased by a factor of 0.125 times the sending rate. The value of S is calculated according to the following formulas:

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Alkenes react with CuBr2 in acetonitrile under mild conditions to produce vicinal dibromoalkanes in an exclusive anti addition 45 Shape-selective bromination of either linear alkenes or branched and cyclic alkenes in the presence of zeolites has been reported 46 In the so-called

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To format a Data Series item and to follow along with the example in this section, complete these steps: 1. Verify that your PivotChart looks like Figure 13-11, then right-click the 3-D cylinder for Accessories and choose Format Data Series from the pop-up menu. 2. Verify that the Format Data Series dialog box in Figure 13-14 appears. 3. Set the Gap Depth and the Gap Width both to 25% on the Series Options tab. 4. Click the Shape tab and choose Partial Pyramid as the shape. 5. Click the Close button to close the Format Data Series dialog box. 6. Verify that your PivotChart looks like Figure 13-15.

as shown in Figure 171, the e-Scientist s environment is composed of data/computation services, information services, and knowledge services However, before we deal with the speci cs of each of these different types of service, it is important to highlight those aspects that are common since this provides the conceptual basis and rationale for what follows To this end, Section 1731 provides the justi cation for a service-oriented view of the different layers of the Semantic Grid Section 1732 then addresses the technical rami cations of this choice and outlines the key technical challenges that need to be overcome to make service-oriented Grids a reality The section concludes (Section 1733) with the e-Science scenario of Section 172 expressed in a service-oriented architecture 1731 Justi cation of a service-oriented view Given the set of desiderata and requirements from Section 17.

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2, a key question in designing and building Grid applications is what is the most appropriate conceptual model for the system The purpose of such a model is to identify the key constituent components (abstractions) and specify how they are related to one another Such a model is necessary to identify generic Grid technologies and to ensure that there can be reuse between different Grid applications Without a conceptual underpinning, Grid endeavours will simply be a series of handcrafted and ad hoc implementations that represent point solutions To this end, an increasingly common way of viewing many large systems (from governments, to businesses, to computer systems) is in terms of the services that they provide Here a service can simply be viewed as an abstract characterization and encapsulation of some content or processing capabilities.

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